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21.
Huimin Zhang Mei Chen Tianmeng Jiang Haiguang Chen Dechao Zhang Yunfeng Sun 《Liquid crystals》2013,40(12):1771-1782
ABSTRACTThe structures of the liquid crystal (LC) molecules have a key role in impacting the electro-optical performance of a polymer dispersed liquid crystal (PDLC) film. In this paper, the relationship between the LC molecular structures and the electro-optical properties of PDLC films is investigated based on an unexplored cyano-terminated tolane compounds (CTTCs) doped E8 LCs/UV polymers system. Due to the high polarity of CTTCs, LCs doped with the cyano-terminated tolane (CTT) molecules exhibit high birefringence and large positive dielectric anisotropy. On the whole, PDLC films doped with the CTT molecules exhibit a lower driving voltage than that doped with the pure E8. More excitingly, PDLC films based on CTT molecules with larger length-to-width ratio and longer conjugated system show higher contrast ratio (CR) and faster response time. Eventually, the mechanism of the effects of CTT-based molecular structures and the relationship between the electro-optical performance of PDLC films and CTT molecules are illustrated. This work paves a new way for optimising the electro-optical properties of PDLC films. 相似文献
22.
林建宗 《数学的实践与认识》2016,(19):62-73
在线声誉机制是网购平台重要的信号机制,是平台可持续成长的基础.从理论基础、研究假设、数据来源、变量选择、模型应用等方面,全面梳理了在线声誉机制作用的实证研究方法,包括Hedonic回归、Logit、Probit、Poisson、Tobit、截取正态回归、样本选择回归、固定效应、广义最小二乘法等模型的应用.最后展望未来相关研究及方法,并构建在线声誉机制作用的实证研究综合框架. 相似文献
23.
The hydrothermal treatment of sugars features a promising technology for the production of fine and platform chemicals from renewable resources. In this work the hydrothermal decomposition of fructose was studied in a buffered medium at a pH range between 2.2 and 8.0. It is demonstrated that at lower pH values mainly 5-hydroxymethylfurfural (HMF), levulinic acid and humin are generated, while lactic acid and acetic acid are produced at higher pH values. The work shows that the use of moderate acidic conditions may have advantages for the hydrothermal HMF production over the use of strongly acidic conditions, as especially the degradation into levulinic acid is suppressed. Besides, this study deals with a rather complex reaction network, hence limitations and need for adaption of the kinetic model are discussed. 相似文献
24.
A method for measuring the spontaneous polarization P s, the switching time, the rotational viscosity γφ, and the d.c. conductivity σ is presented. The possibilities of estimating the azimuthal angle φ0, the dielectric anisotropy δε and the dielectric permittivity ε⊥ in the same experiment are also discussed. It is explicitly shown that the switching delay, though primarily dependent on the material and the applied field, is also dependent on the geometry of the cell. 相似文献
25.
26.
The liquid crystal (LC) alignment properties of LC cells fabricated with films of 2-naphthoxymethyl-substituted polystyrenes with different contents of naphthoxymethyl side groups were investigated. The polymer films exhibited good optical transparency in the visible light region (400–700 nm). The LC cells made from the unrubbed films of polymers having more than 57 mol%?of 2-naphthoxymethyl containing monomeric units showed homeotropic LC alignment with a high pretilt angle of about 90o. Good electro-optical characteristics, such as the threshold voltage, response time, voltage holding ratio and residual DC voltage were observed for the LC cells fabricated with the polymer having 100 mol%?of 2-naphthoxymethyl containing monomeric units as an LC alignment layer. 相似文献
27.
Shashank Tripathi Achu Chandran Tilak Joshi Anil Kumar Ajay Dhar 《Liquid crystals》2013,40(9):1255-1262
In this article, a newly synthesised ferroelectric liquid crystal (FLC) material, namely LAHS 22, has been characterised. The characterisation of the FLC material has been performed using dielectric relaxation spectroscopy, differential scanning calorimetry and polarisation optical microscopy. We observed an enhancement in the dielectric and electro-optical properties of the FLC material by incorporating gold nanoparticles (GNPs)-decorated multiwalled carbon nanotubes (MWCNTs). The GNPs-decorated MWCNTs cause an increment in dielectric dispersion (up to kHz), absorption, spontaneous polarisation and rotational viscosity of the FLC material. The pure and GNPs-decorated MWCNTs doped FLC cells were analysed by means of various dielectric spectroscopic and optical measurements. The observed enhancement in the dielectric and electro-optical properties of the FLC material has also been studied with concentration of GNPs-decorated MWCNTs in FLC material. The GNPs-decorated MWCNTs/FLC composites are not only of fundamental importance, but also useful materials for device applications such as liquid crystal displays and memory devices. 相似文献
28.
Cecile Canlet Bing M. Fung Frederick Roussel Karine Leblanc Philippe Berdague Jean-Pierre Bayle 《Liquid crystals》2013,40(5):635-641
Mesogenic compounds containing four rings in the core usually have very high melting points. However, when two identical lateral benzyloxy groups are introduced on the same side of one of the central rings, the melting point is lowered dramatically and a large nematic range is retained. This range is affected by the bulkiness of the para-substituents in the lateral rings. Methyl groups can be introduced in the ortho- or meta-positions with a consequent decrease in the melting temperature without much affecting the nematic range. These compounds exhibit a rich solid polymorphism which is certainly related to the effect of the conformations of the lateral substituent on the molecular arrangment in the solid phase. Some preliminary NMR experiments on the nematic phase indicate that the molecular long axis coincides with the core axis, whereas the para-axis of the lateral fragment makes an angle close to the magic angle with respect to the molecular long axis. 相似文献
29.
An investigation into the transmission spectrum of a ferroelectric liquid crystal device is undertaken. This is done both for an initial static state and during a switching process. Comparisons are made between experimental data and theoretical predictions. The dynamic internal director configurations in the device is shown to be consistent with a simple model during both monopolar and bipolar addressing pulses. 相似文献
30.
Joaquin Barbera Mercedes Marcos Ana Omenat Jose-Luis Serrano Jesus I. Martinez Pablo J. Alonso 《Liquid crystals》2013,40(2):255-262
The synthesis and liquid crystalline behaviour of the first and second generations of a dendrimeric structure based on poly(propyleneimine)(DAB-dendr(NH2)x) are reported. 4-(4-n-Alkoxybenzoyloxy)salicylaldehydes are used as mesogenic moieties attached at the peripheral amino groups of the dendrimers giving rise to dendromesogens with four and eight mesogenic branches. From these dendromesogens, considered as organic ligands, were prepared six metal-containing dendrimers which incorporate two or four copper atoms in their structures. All the dendrimeric ligands and three of the metal-containing dendrimers exhibit liquid crystalline properties which were studied by optical microscopy, DSC, X-ray diffraction and EPR spectroscopy. 相似文献